Mechanism for the nitration of benzene Assignment Help

Assignment Help: >> Sulfonation and nitration - Mechanism for the nitration of benzene

Mechanism for the nitration of benzene:

The mechanism for the nitration of benzene is extremely identical to sulfonation as shown in figure.

75_Mechanism for the nitration of benzene.png

Figure: Nitration of benzene.

As the aromatic ring create a bond to the electrophilic nitrogen atom, a π bond among the N and O breaks and both electrons move onto the oxygen atom. Not like sulfonation, this oxygen keeps the negative charge of it and does not pick up a proton. This is since it works as a counterion to the neighboring positive charge on nitrogen.

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