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Assignment Help: >> Principle of Thermometric Titrations - Nomenclature

Nomenclature:

Operationally enthalpograms are thermometric titration curves, where temperature is experimentally observable variable upon addition of titrant. The primary property which determines the shape of an enthalpogram is change in enthalpy. That particular accounts for the designation "Thermomatic titration" (TT) and "enthalpy titration" used in literature. Other same terms involve "Calorimetric titration, thermochemical titration, and thermal titration, same to the usage for potentiometric/amperometric techniques.

Another category of thermometric titration involves direct injection enthalpimetry (DIE) that yields a plot of temperature vs the time following injection of the titrant. In this case end point is not obtained but the magnitude of the temperature change is proportional to the concentration. The speed of analysis is enhanced and processes with equilibrium unfavourable for titration are readily studied through using a large excess of one reagent.

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