Stretching vibrations Assignment Help

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Stretching vibrations:

In stretching vibrations, an atoms move along the bond axis so which the bond length increases or decreases at regular intervals. The stretching vibrations again are of two kinds- symmetric and antisymmetric stretching. Within symmetric stretching of a triatomic molecule, both the bonds linked to a general atom either elongate or contract concurrently.  In case of antisymmetric stretching, if one bond is lengthened, the other bond is shortened or vice-versa. The stretching vibrations along with the bending vibrations (discussed below) are displays in Figures, correspondingly for linear and angular molecules of the AB2 type. The arrows attached to each atom show the direction of its motion during half of the vibration; it reverses in the other half.

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Figure: Normal modes of vibrations of a linear triatomic molecule, AB2

2434_Stretching vibrations1.png

Figure: Normal modes of vibrations of an angular triatomic molecule, AB2

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