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Representation of precession of nucleus:

The precessional frequency (ω) also called Larmor frequency is directly proportional to the strength of the external magnetic field (B0). therefore

ω α  B0            or       ω  =  γB0

where, γ is called the magnetogyric (or gyromagnetic)  ratio. It is the ratio of the nuclear magnetic moment (µ) and the nuclear angular momentum (I). i.e., γ = µ/I. The general frequency, ν and the precessional frequency, ω are associated as follows:

ω = 2πv = γ B0                                                                                                         

or    ν =   γ/2π B0=(B0 /2π) .µ/I

After substituting values of I and µ , from Eqs. 1 and 3 respectively, we get the following expression.

ν = g N µN B0/h

Thus, the precessional frequency of the spinning nucleus is exactly equal to the frequency of electromagnetic radiation necessary to induce a transition from one nuclear spin state to another spin state. This fact gives a mechanism of causing the nuclear spin transition.

349_Representation of precession of nucleus.png

Figure: Representation of precession of nucleus in two orientations; aligned to the external magnetic field and opposed to the magnetic field

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