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Formation of ion association complex:
The tetraphenylarsonium cation combines with the permanganate anion to form the complex as shown below:
R4As+a +MnO-4 ↔ (R4As+.MnO4-)a
Kf =[(R4As+.MnO-4)]a/[R4As+]a[MnO4-]a
The value of Kf is small.
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