Ohmic Potential: IR Drop:
Electrochemical cells, such as metallic conductors, resist the flow of charge. In both kinds of conduction, Ohm's law defines the effect of this resistance. The product of the resistance R of a cell in ohms and the current, I in amperes is known as the ohmic potential or the IR drop of the cell.
We know in which while applied potention, Eapplied = Ecell, no current flows by the cell. While you gradually increase the applied potential, a small current appears in the circuit. This current by the cell encounters resistance R resulting in a potential drop of -IR volts. Alternatively, the applied potential must be greater than the theoretical cell potential through -IR volts. Therefore, in the presence of a current, a cell potential must be changed through the addition of the term -IR.
Eapplied = Ecell - IR
Eapplied = Ecathode - Eanode - IR
where Ecathode and Eanode = Ecell are electrode potentials computed along with the Nernst equation.