Faraday:
The quantity of electricity carried by one mole of electrons is called Faraday and is given by the symbol, F. A charge of an electron is l.6022 × l0-19. Therefore the charge on one mole of electrons would be
1.6022 × l0-19 × 6.022 × l023 C or 96485C
Therefore one Faraday = 96485 C or approximately 96,500C.
Now consider a reaction,
Mn+ + ne ? M
The quantity of electricity required for the deposition of 1 mole of a component will be equal to nF, here n is the number of moles of electrons required for the reaction. Now let Mr be the relative atomic mass of one mole atom of an element. Therefore, for the deposition of Mr g (or 1 mole) of the element, we require nF or n × 96,500 C of electricity.
m = (Mr Q /96500 n) g
While m = mass of an element deposited through the passage of Q coulomb of current or
m = (Mr × I × t)/95600 n
This equation is meaningful in calculating the mass of an element deposited through the passage of known quantity of current.