The Schmidt reaction is an organic reaction including alkyl migration on the carbon-nitrogen chemical bond in an azide with removal of nitrogen. A key reagent bringing in this azide group is hydrazoic acid and the reaction product relies on the kind of reactant: Carboxylic acids form amines by an isocyanate intermediate (1) and ketones gives amides (2)
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Reaction mechanism -
![588_schmidt-reaction-mechanism.png](https://www.expertsmind.com/../CMSImages/588_schmidt-reaction-mechanism.png)
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