The metal-ion-catalyzed σ-bond rearrangement reaction takes place with highly saturated organic ring molecules treated with Ag+, Rh(I), or Pd(II) ions. Two kinds of the reaction were found: [2+2] ring openings, and a conversion to the other ring system:
![131_Metal-ion-catalyzed-σ-bond-rearrangement.png](https://www.expertsmind.com/CMSImages/131_Metal-ion-catalyzed-%CF%83-bond-rearrangement.png)
A mechanism for this rearrangement reaction is not totally understood, though some explanations were suggested.
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