The Kulinkovich reaction explains the organic synthesis of cyclopropanols through reaction of esters with dialkyldialkoxytitanium reagents, formed in situ from Grignard reagents bearing hydrogen in beta-position and titanium(IV) alkoxides like titanium isopropoxide. This reaction was founded by Kulinkovich and coworkers in 1989. The titanium reagent can be taken or used catalytically.
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Reaction Mechanism -
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