The Kornblum-DeLaMare rearrangement is a rearrangement reaction in which a primary or secondary organic peroxide is changed to the resultant ketone and alcohol under base catalysis. The reaction is appropriate as a tool in organic synthesis and is a main step in the biosynthesis of prostaglandins.
![1888_Kornblum–DeLaMare-rearrangement.png](https://www.expertsmind.com/../CMSImages/1888_Kornblum–DeLaMare-rearrangement.png)
The base can be a hydroxide like potassium hydroxide or an amine like triethylamine.
![1363_Kornblum–DeLaMare-rearrangement-mehanism.png](https://www.expertsmind.com/CMSImages/1363_Kornblum%E2%80%93DeLaMare-rearrangement-mehanism.png)
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