Kolbe electrolysis or Kolbe reaction is an organic reaction named for the Adolph Wilhelm Hermann Kolbe. The Kolbe reaction is a decarboxylative dimerisation and proceeds through a radical reaction mechanism. Usually, the reaction can be observed as:
R1COO- + R2COO- → R1-R2 + 2 CO2
If R1, R2 are different, then alkanes R1-R1 and R2-R2 are also produced.
As an example, electrolysis of acetic acid gives ethane and carbon dioxide:
CH3COOH → CH3COO- → CH3COO· → CH3· + CO22CH3· → CH3CH3
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