In organic chemistry ketone halogenation is a particular form of halogenation.

The position alpha (next) to the carbonyl group in a ketone is simply halogenated, because of the ability to give an enolate in basic solution, or an enol in acidic solution. An illustration is the bromination of acetone in basic solution:

CH₃-CO-CH₃ + OH^- → CH₃-CO-CH₂^- + H₂O

CH₃-CO-CH₂^- + Br₂ → CH₃-CO-CH₂Br + Br^-

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