In organic chemistry, the Hofmann-Martius rearrangement is a rearrangement reaction changing an N-alkylated aniline to the corresponding ortho and / or para aryl-alkylated aniline. The reaction needs heat and the catalyst is an acid such as hydrochloric acid.
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When the catalyst is a metal halide the reaction is also known as the Reilly-Hickinbottom rearrangement.
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