Hemetsberger indole synthesis (also referred as the Hemetsberger-Knittel synthesis) is a chemical reaction that thermally decomposes a 3-aryl-2-azido-propenoic ester to an indole-2-carboxylic ester.
Yields are usually above 70%. Though, this is not a popular reaction, because of the lack of stability and difficulty in synthesizing the starting material.
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