Glycol cleavage is a special type of organic chemistry oxidation. The carbon-carbon bond in a vicinal diol (glycol) is cleaved and moved with two carbon-oxygen double bonds. On the basis of substitution pattern in the diol, either ketones or aldehydes can be formed.
Glycol cleavage is a significant reaction in the laboratory as it is useful for knowing the structures of sugars. After cleavage occurs the ketone and aldehyde fragments can be inspected and the location of the former hydroxyl groups determines.
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