The Emde degradation (also known as Emde-reaction or Emde-reduction) is a process for the reduction of a quaternary ammonium cation to a tertiary amine with sodium amalgam.
This organic reaction was earliest described in 1909 by the German chemist Hermann Emde and was for a long time of huge importance in structure elucidation of various alkaloids, for instance that of ephedrine.
Alternative reducing agents available for this reaction; for example, lithium aluminium hydride.
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