An electrophilic aromatic halogenation is a form of electrophilic aromatic substitution. This organic reaction is characteristic of aromatic compounds and a very functional method for adding substituents to an aromatic system.
![915_Electrophilic-halogenation.png](https://www.expertsmind.com/../CMSImages/915_Electrophilic-halogenation.png)
A few types of aromatic compounds, like phenol, will react withno catalyst, but for typical benzene derivatives with less reactive substrates, a Lewis acid catalyst is necessary. Typical Lewis acid catalysts comprise AlCl3, FeCl3, FeBr3, and ZnCl2. These work by making a highly electrophilic complex which attacks the benzene ring.
Reaction mechanism-
![41_Electrophilic-halogenation-mechanism.png](https://www.expertsmind.com/../CMSImages/41_Electrophilic-halogenation-mechanism.png)
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