The di-pi-methane rearrangement is a photochemical reaction of a molecular entity including two π-systems, divided by a saturated carbon atom (a 1,4-diene or an allyl-substituted aromatic analog), to give an ene- (or aryl-) substituted cyclopropane. The rearrangement reaction properly amounts to a 1,2 transfer of one ene group (in the diene) or the aryl group (in the allyl-aromatic analog) and bond formation among the lateral carbons of the non-migrating moiety.
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Reaction Mechanism-
![1695_Di-pi-methane-rearrangement-mechanism.png](https://www.expertsmind.com/CMSImages/1695_Di-pi-methane-rearrangement-mechanism.png)
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