Dess-Martin periodinane (DMP) is a chemical reagent utilized to oxidize primary alcohols into aldehydes and secondary alcohols to ketones. This periodinane has numerous advantages over chromium- and DMSO-based oxidants that comprise milder conditions (room temperature, neutral pH), higher yields, shorter reaction times, simplified workups, tolerance of sensitive functional groups, high chemoselectivity, and a long shelf life. It is named for the American chemists Daniel Benjamin Dess and James Cullen Martin who found the reagent in 1983.
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