The Carbylamine reaction is a chemical test for identification of primary amines. In this reaction, the analyte is heated along with alcoholic potassium hydroxide and chloroform. If a primary amine is present, the isocyanide is produced.
For instance, the reaction with ethylamine:
![1887_Carbylamine-reaction.png](https://www.expertsmind.com/../CMSImages/1887_Carbylamine-reaction.png)
The reaction with aniline:
![1266_Carbylamine-reaction1.png](https://www.expertsmind.com/CMSImages/1266_Carbylamine-reaction1.png)
The carbylamine test does not provide a positive reaction with secondary and tertiary amines
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