The Benkeser reduction organic reaction is the catalytic hydrogenation of polycyclic aromatic hydrocarbons, particularly naphthalene utilizing lithium or calcium metal and any of the subsequent primary amines or low molecular weight alkyl groups as reductants: -CH₃, -CH₂CH₃, -CH₂CH₂CH₃, -CH₂CH₂NH₂.

This reaction is a amendment of the Birch reduction.

Its products involve bicyclo[3.3.0]dec-(1,2)-ene, bicyclo[3.3.0]dec-(1,9)-ene, and bicyclo[3.3. 

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