The alkyne zipper reaction is a reaction which isomerizes an organic compound comprising of an internal alkyne to a terminal alkyne. This was initially reported by Ayako Yamashita and Charles Allen Brown in 1975. The isomerization reaction starts for straight-chain alkynes and acetylinic alcohols and gives a valuable approach for remote functionalization in long-chain hydrocarbons.

HO-CH₂C≡C-(CH₂)₆CH₃ → HO(CH₂)₈-C≡CH

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