Intensity Concentration Relationship:
The intensity of the emitted radiation (P) is proportional to the number of excited atoms N*.
P ∝ N*
P = a. N* (where a is the proportionality constant)
Again, from Eq, we see that the number of atoms in the excited state, N*, at a given temperature are proportional to N0. Thus, we can write the following.
P = a. N0 =g*/g0e-ΔE/kT( as N* = N0 =g*/g0e-ΔE/kT)
P = K. N0(K=a. g*/g0e-ΔE/kT)
P = K′. C (as, N0 is directly proportional to metal concentration) Therefore, the intensity of the emitted light will be directly proportional to the concentration of the element introduced within the flame.