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Trace metals
Necessary elements of the d block are mainly components of specialized metalloproteins that give coordination sites with suitable ligand atoms (O, N or S) in favorable geometrical arrangements for complexing a specific metal ion. The significant element iron is available in heme proteins containing the group displayed in diagram 1a and in iron-sulfur proteins containing groups like the 4Fe-4S cluster displayed in Fig. 1c. Several metalloproteins are enzymes with a catalytic role.
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