Quantitative Applications:
You have learnt in which how UV-VIS spectrometry could be used for quantitative determinations. Within case of IR spectrometry the quantitative use is subject to a number of practical and instrumental problems. A few of these are as follows:
- Narrowness of the IR bands
- Low intensity of the source and low sensitivity of the transducer
- Non availability of the matched cells for the sample and reference
- Interference by solvents and IR absorbing air contaminants
In the light of these factors the quantitative application of IR needs a thorough planning of the experiment and a skilled execution of the procedure to obtain the spectrum. Therefore in case of FT-IR, the results are much better. Further, the method of concurrent determination could also be used for quantitative analysis using IR spectrometry.
A number of easy, portable and yet dependable IR spectrometers are available which might be used to quantitatively analyse a mixture of gaseous pollutants in a short time. These instruments are IR filter photometers and provide good results but not as good as are probable along with UV-VIS spectrophotometers.