Examples of Amperometric Titration:

 Determination of Zinc with EDTA Reagents required

i)          0.005 M zinc ion solution

ii)        0.01 M EDTA solution

iii)       Cyclohydoxylamine

The titrant should be lean 10 times strong than the ion taken in the cell. Procedure: Place 5.00 cm³ of zinc ion solution in the titration cell, add 1.0 cm³ of cyclohexylamine or 19.0 cm³ of distilled water and set the applied potential at -1.4 V vs SCE corresponding to Zn²⁺. Deaerate the solution and titrate with standard EDTA solution. Pass N₂ for 1 minute after that take readings of both burette and the galvanometer. Huge initial current will be decreased as the titration proceeds to a extremely small value at the equivalence point and remains constant beyond the equal point. Use volume correction and plot the readings. The graph is as display in the titration curve. (1 ml of 0.01 M EDTA of Zn = 0.0006537 g of Zn.)