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Chemistry of Nitriles:
Preparation
Nitriles are generally prepared through the SN2 reaction of a cyanide ion along with a primary alkyl halide. Though, this limits the nitriles that can be synthesized to those having the following common formula RCH2CN. A much more general synthesis of nitriles includes the dehydration of primary amides with reagents like thionyl chloride or phosphorus pentoxide as shown in diagram.
Figure: Dehydration of primary amides with thionyl chloride.
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