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Q. The equilibrium cell potential of the galvanic cell
is found to be Ecell,eq = 1.410 V at 298.15K. The standard cell potential is Ecell,eq = 1.360V.
(a) Write the cell reaction and calculate its thermodynamic equilibrium constant at 298.15K.
(b) Use the cell measurement to calculate the mean ionic activity coefficient of aqueous HCl at 298.15K and a molality of 0.500 mol kg-1.
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The standard EMF of Pt/H2(g)/HCl(aq)//AgCl(aq)/Ag has been experimentally determined from 0-90?C to yield the following; E?/V =0.23659 – 4.856 * 10-4t(?C) – 3.4205 * 10-4t2(?C) +
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