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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
how it works, give me some examples
parts of ac generator
Q. What are Changes in Matter? Matter is able to undergo two fundamental kinds of changes. Changes that don't alter the composition of matter are called physical changes. Sta
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387 J/Kg. C or 0.0924 Cal/g.C
Q. Illustrate about square planar complexes? For square planar complexes Mu, Ma3b or Mab3 where a and b etc., are monodentate ligands, again the geometrical isomerism is not p
The diffusion current for a standard 1 x 10-4 M solution of hydroquinone is found to be 17.5 µA. An unknown solution of hydroquinone, when diluted tenfold and analysed under simila
PREPARATIONS OF DIENES
What is the reliablitiy of redox titrations?
Q. Test for the presence of linseed oil? Hexabromide test is done to know the extent of presence of linolenic acid. In presence of fish oils, which are rich in linolenic acid,
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