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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
For an electron if the uncertainty in velocity is Δ v , the uncertainty in its position( Δ x ) is given by: (1) hm/ 4 Π Δ b (2) 4 Π / hm Π v
For d electrons, the azimuthal quantum number is: (1) 0 (2) 1 (3) 2 (4) 3 Ans: 2
In the Lectures where the necessary heat transfer area for the production of aspirin was being discussed, we had calculated (a) the volume of the scaled up version of the tank and
CRYSTALLINE SOLIDS Solids may be loosely categorized into two groups. Amorphous solid has no long-range order in their molecular or atomic structure. By their nature Amorphous
Compounds and IUPAC names
Formaldehyde: Formaldehyde is the initial member of the aldehyde sequence. It is lie in green leaves of plants where its presence is supposed to be due to the reaction of with w
How are p-type and n-type semiconductor obtained? A P-type semiconductor is attained by carrying out a process of doping which is adding a certain type of atoms to the semicon
#quest what is castner kellner procession..
In polar covalent molecule, one atom gets positive charge and the other one takes negative charge as known as dipole.
Experimental evidence for the existence of the atomic nucleus comes from: (1) Millikan's oil drop experiment (2) Atomic emission spectroscopy (3) The magnetic bending of
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