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The order of a reaction is occasionally changed by conditions. Consider a chemical reaction between two substances where one reactant is there in large excess. During the hydrolysis of 0.01 mol of ethyl acetate with 10 ml of water, amounts of the various constituents at the beginning (t = 0) and complexion (t) of the reaction are given as under The concentration of water does not get altered much during the course of the reaction. So, in the rate equation Rate = k’ [CH3COOC2H5] [H2O] The term [H2O] can be taken as constant. The equation, thus, becomes Rate = k [CH3COOC2H5] Where k = k’ [H2O] And the reaction behaves as first order reaction. Such reactions are called pseudo first order reaction. Conversion of cane sugar is one more pseudo first order reaction. Rate = k [C12H22O11]
The number of d electrons in Fe +2 (atomic number of Fe= 26 ) is not equal to that of the: (1) p-electrons in Ne (At. No.= 10) (2) s-electrons in (At. No.= 12)
Uses of Benzaldehyde - Aldehydes and Ketones Benzaldehyde is used, (a) In perfumery (d) In manufacture of dyes (c) In preparation of benzoic acid, cinnamic acid, cinna
why they have low electronegativity?
why is density of interstitial compounds less than that of parent metal ?
Major modes of food deterioration During storage and distribution, foods are exposed to a wide range of environmental conditions. Environmental factors such as temperature, hum
in ecm some have positive eo values
explain the principle of EDTA method
is vinegar has a pungent odor. is it chemical or physical property?
which is the main postulate of bohr''s model of atom
When the azimuthal quantum number has a value of l=0 , the shape of the orbital is: (1) Rectangular (2)Spherical (3)Dumbbell (4)Unsymmetrical Ans: Spherical
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