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The order of a reaction is occasionally changed by conditions. Consider a chemical reaction between two substances where one reactant is there in large excess. During the hydrolysis of 0.01 mol of ethyl acetate with 10 ml of water, amounts of the various constituents at the beginning (t = 0) and complexion (t) of the reaction are given as under The concentration of water does not get altered much during the course of the reaction. So, in the rate equation Rate = k’ [CH3COOC2H5] [H2O] The term [H2O] can be taken as constant. The equation, thus, becomes Rate = k [CH3COOC2H5] Where k = k’ [H2O] And the reaction behaves as first order reaction. Such reactions are called pseudo first order reaction. Conversion of cane sugar is one more pseudo first order reaction. Rate = k [C12H22O11]
Side chain - nomenclature of simple aromatic compounds The alkyl or any other aliphatic group consisting of at least one carbon atom attached to the nucleus is termed as side c
the carbonate process
Beckmann rearrangement Ketoxime while treated with acid at 0° C it goes through rearrangement termed as Beckmann rearrangement. So, acid catalysed conversion of ketoximes t
How many ion H2- does have The H2- ion having three electrons. This can be conceived as the combination of a hydrogen atom with a hydride ion (H-). By the aufbau principle, two
Problem 1: Describe TDM and mention its clinical significance in clinical practice. Definition of TDM Show the importance of TDM and its clinical significance in clini
Colloids are either positively charged or negatively charged. But What are the various factors responsible for charge on the colloidal sols?
conductometric determination of hydrolysis constant of conjugate base of weak acid experiment?
Write the periods of periodic table have d-block element
what is trasitions elements
The set of quantum numbers not applicable for an electron in an atom is: (1) n= 1, l=1, m 1 = 1, m s = +1/2 (2) n= 1, l=0, m 1 = 0, m s = +1/2 (3) n= 1, l=0 m
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