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Q. What is Pairing energy explain?
Pairing energy, P, depends mainly on the electronic distribution of the central metal ion and its value can be obtained from the atomic spectra of the element. The D0 obtained from the molecular spectra of the complex. It depends on the metal ion, ligand and the geometry of the complex. Once these two values are known for any complex, you will know whether it will be high spin or low spin and you will also be able to calculate the CFSE. Table 14.6 gives the pairing energy values ford to d7 ions of first row transition elements as well as values for a few complexes. In dl,d 2, d3, d8. d9 and dl0 systems only one configuration each is possible.
Calculate the molarmass of a nonelectrolyte that lowers the freezing point of 25.00g of water to -3.9 degrees C when 4.27 g of the substance is dissolved in the water.
?H value obtained for the reaction NH3 + HCl –› NH4Cl using the thermodynamic data in your lab procedure?
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What is T in the indicator Eriochrome Black-T used for the determination of hardness of water?
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Explain the following observations: (i) Generally there is an increase in density of elements from titanium (Z = 22) to copper (z =29) in the first series of transition element
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Q. Define the Spectrochemical series? Spectrochemical series helps us in renationalising the differences in the spectral properties of complexes. As the strength of the crystal
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