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Q. What is Pairing energy explain?
Pairing energy, P, depends mainly on the electronic distribution of the central metal ion and its value can be obtained from the atomic spectra of the element. The D0 obtained from the molecular spectra of the complex. It depends on the metal ion, ligand and the geometry of the complex. Once these two values are known for any complex, you will know whether it will be high spin or low spin and you will also be able to calculate the CFSE. Table 14.6 gives the pairing energy values ford to d7 ions of first row transition elements as well as values for a few complexes. In dl,d 2, d3, d8. d9 and dl0 systems only one configuration each is possible.
define pi acid ligand
Briefly discuss the physical origin and uses of Hall effect? Its physical origin follows from the Boltzmann Transport phenomenon. It is used to get carrier density and the sign
Q. Determine the equilibrium constant? At 298 K, the molar conductivities at infinite dilution of NH 4 Cl, NaOH and NaCl are 129.8,217.4 and 108.9 ohm -1 cm 2 mol -1 respect
Q. What is the use of Gallium? Gallium is mainly used in semiconductor technology. It is used for doping other semiconductor and in solid state devices such as transistors.
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The following information is available for the extraction of Cu2+ into CCl4 with dithizone: KD,c = 7 ´ 104; b = 5 ´ 1022; Ka,HL = 3 ´ 10–5; KD,HL = 1.1 ´ 104; n = 2. What is the ex
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