What is hydrate isomerism, Chemistry

Assignment Help:

Q. What is Hydrate Isomerism?

In a compound, water molecules may be present in either coordinated form or as water of crystallisation In the former case water  molecules are directly attached to the metal ion, or in the latter case they may occupy lattice sites in a crystal without getting attached to the metal ion. This type of isomerism is known as hydrate isomerism and the physical and chemical properties of hydrate isomers are quite different. As an example, we consider at least three well established isomers of a complex CrCl3.6H2O these are:

(i) [Cr (H20)4Cl2] Cl2H20, a dark green compound where four molecules of water are coordinated to Cr (III) ion and the other two molecules occupy the lattice position..

(ii) [Cr (H20)5CI] Cl2.H20 is blue green in colour and has five coordinated and one lattice molecules of water.

iii) [Cr(H2O) 6[ Cl3 is violent in colour and all the molecules of  water are coordinated.

A few other examples are:

[Co (NH3)4(H20)CI]Br2, [Co(NH3)4Br2]CI-H20  and

[Co(NH3)3(H20)2CI]Br:. [Co(NH3)3Br2 (H2O)IBr.H20


Related Discussions:- What is hydrate isomerism

Chemical Bonding, Structure of chlorine triflouride by VSEPR theory

Structure of chlorine triflouride by VSEPR theory

Alkaline metals, why sodium react with water form a fair

why sodium react with water form a fair

Illustrate phase diagram, Q. Illustrate phase diagram? Ans. Ther...

Q. Illustrate phase diagram? Ans. There are two things which influence phase change: 1. The pressure exerted on the surface of a substance. 2. The addition or rele

Water were uniformly distributed on earth surface, If the water molecules i...

If the water molecules in 1g of water were uniformly distributed on earth surface , how many such water molecules would there be in 1 cm^2 of earth? Solution) No. of molecules in

Ion, How ion works?

How ion works?

Describe about tetrahalides, Q. Describe about tetrahalides? S, Se, Te ...

Q. Describe about tetrahalides? S, Se, Te and Po form tetrahalides with all the halogens. However, tetrafluoride of polonium, tetrabromide of sulphur and tetraiodides of sulphu

#tit4-pyridinecarboxaldehyde.., synthesis, posted date 1/12/2013 7;26;41 pm...

synthesis, posted date 1/12/2013 7;26;41 pm\location ;austeralia

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd