What is hydrate isomerism, Chemistry

Assignment Help:

Q. What is Hydrate Isomerism?

In a compound, water molecules may be present in either coordinated form or as water of crystallisation In the former case water  molecules are directly attached to the metal ion, or in the latter case they may occupy lattice sites in a crystal without getting attached to the metal ion. This type of isomerism is known as hydrate isomerism and the physical and chemical properties of hydrate isomers are quite different. As an example, we consider at least three well established isomers of a complex CrCl3.6H2O these are:

(i) [Cr (H20)4Cl2] Cl2H20, a dark green compound where four molecules of water are coordinated to Cr (III) ion and the other two molecules occupy the lattice position..

(ii) [Cr (H20)5CI] Cl2.H20 is blue green in colour and has five coordinated and one lattice molecules of water.

iii) [Cr(H2O) 6[ Cl3 is violent in colour and all the molecules of  water are coordinated.

A few other examples are:

[Co (NH3)4(H20)CI]Br2, [Co(NH3)4Br2]CI-H20  and

[Co(NH3)3(H20)2CI]Br:. [Co(NH3)3Br2 (H2O)IBr.H20


Related Discussions:- What is hydrate isomerism

Bohr model of an atom could not account for, Bohr model of an atom could no...

Bohr model of an atom could not account for : (1) Emission spectrum   (2) Absorption spectrum   (3) Line spectrum of hydrogen  (4)Fine spectrum Ans:  Fine spectrum

Why nh4+ ion doesnot form complexes? , Explain ,Why NH 4 + ion doesnot fo...

Explain ,Why NH 4 + ion doesnot form complexes? solution) NH 4 + Ion does not act as ligand because nitrogen atom has no lone pair of electrons which it can donate to metal a

Dehydration., the complete equation for forming a peptide bond through dehy...

the complete equation for forming a peptide bond through dehydration

What are distinguishing characteristics of metallic bonding, What are disti...

What are distinguishing characteristics of metallic bonding?  Metallic  state  can  be  visualized  like an  array  of positive  ions,  with  a  common  pool  of electrons to

Diagram, caustic embrittlement

caustic embrittlement

Iupac nameing, Sir any method to learn the arrangement of functional group ...

Sir any method to learn the arrangement of functional group in poly functional compound ????

Compound formular, Write the formula and name the example of k peroxide

Write the formula and name the example of k peroxide

Laws of chemical combination, how many grams of silicon are present in 35 g...

how many grams of silicon are present in 35 grams of silicon?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd