What is hydrate isomerism, Chemistry

Assignment Help:

Q. What is Hydrate Isomerism?

In a compound, water molecules may be present in either coordinated form or as water of crystallisation In the former case water  molecules are directly attached to the metal ion, or in the latter case they may occupy lattice sites in a crystal without getting attached to the metal ion. This type of isomerism is known as hydrate isomerism and the physical and chemical properties of hydrate isomers are quite different. As an example, we consider at least three well established isomers of a complex CrCl3.6H2O these are:

(i) [Cr (H20)4Cl2] Cl2H20, a dark green compound where four molecules of water are coordinated to Cr (III) ion and the other two molecules occupy the lattice position..

(ii) [Cr (H20)5CI] Cl2.H20 is blue green in colour and has five coordinated and one lattice molecules of water.

iii) [Cr(H2O) 6[ Cl3 is violent in colour and all the molecules of  water are coordinated.

A few other examples are:

[Co (NH3)4(H20)CI]Br2, [Co(NH3)4Br2]CI-H20  and

[Co(NH3)3(H20)2CI]Br:. [Co(NH3)3Br2 (H2O)IBr.H20


Related Discussions:- What is hydrate isomerism

Crystal field splitting in tetrahedral field, Q. Crystal Field Splitting in...

Q. Crystal Field Splitting in Tetrahedral Field? A tetrahedron can be viewed as a part of cube where the metal ion occupies the centre of the cube and the four ligands are plac

Benzaldehyde - aldehydes and ketones, Benzaldehyde - Aldehydes and Ketones ...

Benzaldehyde - Aldehydes and Ketones Benzaldehyde is simple aromatic aldehyde. It occurs in bitter almonds in the type of its glucoside, amygdalin (C 20 H 27 O 11 N). While amy

Determine the spectral lines correspond to paschen series, The emission spe...

The emission spectrum of hydrogen is found to satisfy the expression for the energy change. teiangle E  (in joules) such thatTriangle E= 2.18x10(1/n 2 1 - 1/ n 2 1 ) J  where n

Semisynthetic polymers - classification of polymers, Semisynthetic polymers...

Semisynthetic polymers These polymers are mainly derived from naturally taking place polymers by chemical changes. Since cellulose is naturally taking place polymers, cellulose

Dyeing of fabrics , how to dye a cotton and wool cloth with aniline yellow?...

how to dye a cotton and wool cloth with aniline yellow?

Nerst equation, Derive Nerst equation for both anode and cathode.

Derive Nerst equation for both anode and cathode.

Total number of unpaired electrons in an atom, Total number of unpaired ele...

Total number of unpaired electrons in an atom of atomic number 29 is: (1) 1        (2) 3        (3) 4        (4) 2 Ans: 1

Determine the change in entropy of the system, Two compartments each of 1m ...

Two compartments each of 1m 3 capacity are connected by a valve and insulated from the surroundings and from each other. One compartment contains saturated steam at 683.6 kPa and

Corey-house reaction, assignment in the topic of corey house reaction

assignment in the topic of corey house reaction

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd