What is hydrate isomerism, Chemistry

Assignment Help:

Q. What is Hydrate Isomerism?

In a compound, water molecules may be present in either coordinated form or as water of crystallisation In the former case water  molecules are directly attached to the metal ion, or in the latter case they may occupy lattice sites in a crystal without getting attached to the metal ion. This type of isomerism is known as hydrate isomerism and the physical and chemical properties of hydrate isomers are quite different. As an example, we consider at least three well established isomers of a complex CrCl3.6H2O these are:

(i) [Cr (H20)4Cl2] Cl2H20, a dark green compound where four molecules of water are coordinated to Cr (III) ion and the other two molecules occupy the lattice position..

(ii) [Cr (H20)5CI] Cl2.H20 is blue green in colour and has five coordinated and one lattice molecules of water.

iii) [Cr(H2O) 6[ Cl3 is violent in colour and all the molecules of  water are coordinated.

A few other examples are:

[Co (NH3)4(H20)CI]Br2, [Co(NH3)4Br2]CI-H20  and

[Co(NH3)3(H20)2CI]Br:. [Co(NH3)3Br2 (H2O)IBr.H20


Related Discussions:- What is hydrate isomerism

Which statement is not correc, Which statement is not correct for n=5, m=3:...

Which statement is not correct for n=5, m=3: (1) l=4                    (2) l=0, 1.3, s =+1/2            (3) l= 3                  (4) All are correct Ans:l=4

Titration, How are standard solutions prepared in industries?

How are standard solutions prepared in industries?

Analysis of metabolic components , 1. Produce a figure with an appropriate ...

1. Produce a figure with an appropriate figure legend of your SDS-PAGE gel that could be published in a scientific journal.   Indicate all relevant information, e.g.origin, f

What are changes in matter, Q. What are Changes in Matter? Matter is ab...

Q. What are Changes in Matter? Matter is able to undergo two fundamental kinds of changes. Changes that don't alter the composition of matter are called physical changes. Sta

Chlorine is electron, Although cholrine is electoon withdrawing group.yet i...

Although cholrine is electoon withdrawing group.yet it is ortho nd para directing in electrophilic aromatic substitution reactants.why? Ans) Halogens are an exception of the dea

Acid-base aqueous titrations, what are the conditions of double indicator t...

what are the conditions of double indicator titrations??

Food chemistry, discuss the dietary functional properties of calcium in foo...

discuss the dietary functional properties of calcium in foods

Naming complex substituents - iupac system of nomenclature, Naming complex ...

Naming complex substituents - IUPAC system of nomenclature If the substituent on the parent chain is complex ( that is it is branched) it is termed as substituted alkyl g

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd