What is hydrate isomerism, Chemistry

Assignment Help:

Q. What is Hydrate Isomerism?

In a compound, water molecules may be present in either coordinated form or as water of crystallisation In the former case water  molecules are directly attached to the metal ion, or in the latter case they may occupy lattice sites in a crystal without getting attached to the metal ion. This type of isomerism is known as hydrate isomerism and the physical and chemical properties of hydrate isomers are quite different. As an example, we consider at least three well established isomers of a complex CrCl3.6H2O these are:

(i) [Cr (H20)4Cl2] Cl2H20, a dark green compound where four molecules of water are coordinated to Cr (III) ion and the other two molecules occupy the lattice position..

(ii) [Cr (H20)5CI] Cl2.H20 is blue green in colour and has five coordinated and one lattice molecules of water.

iii) [Cr(H2O) 6[ Cl3 is violent in colour and all the molecules of  water are coordinated.

A few other examples are:

[Co (NH3)4(H20)CI]Br2, [Co(NH3)4Br2]CI-H20  and

[Co(NH3)3(H20)2CI]Br:. [Co(NH3)3Br2 (H2O)IBr.H20


Related Discussions:- What is hydrate isomerism

Chemistry behind the reactions of confirmatory test, what is the chemistry ...

what is the chemistry behind the reactions of confirmatory test of sulphide radical of dilute acid group.

Topic 9 oxidation-reduction, which quantities are conserved in all oxidatio...

which quantities are conserved in all oxidation-reduction reactions

Acid, all alkalis are bases but all bases are not alkalies?

all alkalis are bases but all bases are not alkalies?

Explain haber-bosch process, Haber-Bosch Process Ammonia is one of the ...

Haber-Bosch Process Ammonia is one of the most significant intermediates. It is used, for example, for the production of fertilizers. Usually, ammonia is formed from hydrogen a

Honey, fiehes test means result if positive result always color change if n...

fiehes test means result if positive result always color change if negative color change or not

Periodic table, how periodic table is helpful in chemistry give two example...

how periodic table is helpful in chemistry give two example

Colloids, conclusion for assignment on topic applications of colloids

conclusion for assignment on topic applications of colloids

Explain triene-triol isomer, This compound, 1,3,5-cyclohexanetrione, exists...

This compound, 1,3,5-cyclohexanetrione, exists as its "triene-triol" isomer phloroglucinol because the latter is aroma

Ethane, method of preparation and characteristics of ethane

method of preparation and characteristics of ethane

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd