Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Half life of reaction refers to as the time during which the concentration of the reactants is reduced to half of the initial concentration or it is the time essential for the completion of half of the reaction. It is denoted by 11/2. Half life of zero order reaction: as already discussed, the integrated equation for zero order reaction is; [R] = [R]0 – kt Now at t1/2, [R] = ([R]0)/2 ∴ ([R]0)/2 = [R]0 – kt Or, kt1/2 = [R]0 – ([R]0)/2 = ([R]0)/2 Or, t1/2 = ([R]0)/2k From the above expression it is clear that the half life of a zero order reaction is directly proportional to initial concentration. i.e. t1/2 [A]0 At t3/4, the concentration [R] = ¼ [R]0 t3/4 = 1/k R0- 1/4[R]0) = 3/4 [R0)/k Hence, t3/4 = 3/2 t1/2 = 1.5t1/2 Half life of first order reaction: for first order reaction, we know that k = 2.303/t log ([A]_0)/([A]) or t = (2.303)/k log ([A]_0)/([A]) When t = t1/2 then [A] = ½ [A]0, Therefore, t1/2 = (2.303)/k ½ ([A]_0)/([A]) = (2.303)/k log 2 t1/2 = 0.693/k [? log 2 = 0.3010] It is quite clear from the above expression that the half life or half change time for first order reaction does not depend upon initial concentration of the reactants. Likewise, the time required to decrease the concentration of the reactant to any fraction of the initial concentration for the first order reaction is also independent of the initial concentration.
the carbonate process
conductometric titratins : weak base within a weak acid
What do you understand by Miller indices of a crystal plane? Miller Indices are a symbolic vector representation for the orientation of an atomic plane in a crystal lattice an
Wurtz reaction and Allylic bromination by N-Bromosuccinimide (A) Wurtz reaction - Ethyl bromide on treatment along with metallic sodium forms butane, ethane and ethylene by inc
Alkyl halide on reaction with dry silver oxide
An excess of NaOH solution was added to 100 ml of a ferric chloride solution. This caused the precipitation of 1.425 gram of Fe(OH)3 . calculate the normality of ferric chloride so
name 5 organic compound that can be purify using simple distillation
How to calculate angle strain in. cyclobutane?
Rice bran Rice bran contains primarily insoluble fiber (cellulose) and soluble fiber (hemicellulose). Insoluble fiber adds bulk to the gastrointestinal (GI) track in humans cau
factors affecting TLC in points
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd