What is half life of reaction and how it can calculated? , Chemistry

Assignment Help:

 

Half life of reaction refers to as the time during which the concentration of the reactants is reduced to half of the initial concentration or it is the time essential for the completion of half of the reaction. It is denoted by 11/2.

Half life of zero order reaction: as already discussed, the integrated equation for zero order reaction is;
                                               
[R] = [R]0 – kt
                                    
Now at t1/2, [R] = ([R]0)/2
                                                             
  ([R]0)/2 = [R]0 – kt
                          
Or, kt1/2 = [R]0 – ([R]0)/2 = ([R]0)/2
                                          
Or, t1/2 = ([R]0)/2k


From the above expression it is clear that the half life of a zero order reaction is directly proportional to initial concentration.
                                                   
i.e. t1/2 [A]0
                                  
At t3/4, the concentration [R] = ¼ [R]0
                                    
t3/4 = 1/k R0-  1/4[R]0) = 3/4 [R0)/k 
                                         
Hence, t3/4 = 3/2 t1/2 = 1.5t1/2

Half life of first order reaction: for first order reaction, we know that
                                    
k = 2.303/t log ([A]_0)/([A]) or t = (2.303)/k log ([A]_0)/([A])
                                        
When t = t1/2 then [A] = ½ [A]0,
                                     
Therefore, t1/2 = (2.303)/k ½ ([A]_0)/([A]) = (2.303)/k  log 2
                                        
t1/2 = 0.693/k           [? log 2 = 0.3010]

It is quite clear from the above expression that the half life or half change time for first order reaction does not depend upon initial concentration of the reactants. Likewise, the time required to decrease the concentration of the reactant to any fraction of the initial concentration for the first order reaction is also independent of the initial concentration.


Related Discussions:- What is half life of reaction and how it can calculated?

Sublimation, How can sublimation be useful? Ex. It can be used by ... ...

How can sublimation be useful? Ex. It can be used by ... to...

Simple distillation - purification of organic compounds, Simple Distillatio...

Simple Distillation - Purification of organic compounds Distillation is the joint procedure of vapourisation and condensation. This method is employed for the purification o

Atoms and molecules, can i have some problems regarding law of conservation...

can i have some problems regarding law of conservation of mass

Aromaticity, compare the acidity between pyrole and pyrimidine

compare the acidity between pyrole and pyrimidine

Benzoyl peroxide dissociation, Given below  the values below for the activa...

Given below  the values below for the activation energies of benzoyl peroxide dissociation, styrene propagation, and styrene termination, and suppose all other parameters remain co

Assignment, Applications of radiometric titration in pharmaceutical industr...

Applications of radiometric titration in pharmaceutical industry #

Describe about groups or families in periodic table, Q. Describe about grou...

Q. Describe about groups or families in periodic table? Every element may be represented by a one or two letter symbol. In the middle of nineteenth century a Russian chemist Dm

Drying of organic substances - for liquids, For liquids - Drying of Organic...

For liquids - Drying of Organic Substances Organic liquids are usually dried by keeping them over night in contact along with a dehydrating (desiccating) agent that does not re

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd