What is half life of reaction and how it can calculated? , Chemistry

Assignment Help:

 

Half life of reaction refers to as the time during which the concentration of the reactants is reduced to half of the initial concentration or it is the time essential for the completion of half of the reaction. It is denoted by 11/2.

Half life of zero order reaction: as already discussed, the integrated equation for zero order reaction is;
                                               
[R] = [R]0 – kt
                                    
Now at t1/2, [R] = ([R]0)/2
                                                             
  ([R]0)/2 = [R]0 – kt
                          
Or, kt1/2 = [R]0 – ([R]0)/2 = ([R]0)/2
                                          
Or, t1/2 = ([R]0)/2k


From the above expression it is clear that the half life of a zero order reaction is directly proportional to initial concentration.
                                                   
i.e. t1/2 [A]0
                                  
At t3/4, the concentration [R] = ¼ [R]0
                                    
t3/4 = 1/k R0-  1/4[R]0) = 3/4 [R0)/k 
                                         
Hence, t3/4 = 3/2 t1/2 = 1.5t1/2

Half life of first order reaction: for first order reaction, we know that
                                    
k = 2.303/t log ([A]_0)/([A]) or t = (2.303)/k log ([A]_0)/([A])
                                        
When t = t1/2 then [A] = ½ [A]0,
                                     
Therefore, t1/2 = (2.303)/k ½ ([A]_0)/([A]) = (2.303)/k  log 2
                                        
t1/2 = 0.693/k           [? log 2 = 0.3010]

It is quite clear from the above expression that the half life or half change time for first order reaction does not depend upon initial concentration of the reactants. Likewise, the time required to decrease the concentration of the reactant to any fraction of the initial concentration for the first order reaction is also independent of the initial concentration.


Related Discussions:- What is half life of reaction and how it can calculated?

Explain the term acceptance tests, Acceptance tests What are Acceptanc...

Acceptance tests What are Acceptance Tests? Acceptance tests are used to evaluate product acceptability or liking or to determine which of a series of products is the most acc

Antifertility, how can they used and what its side effects?

how can they used and what its side effects?

Stoichiometry, How do i calculate the number of grams of CO that can react ...

How do i calculate the number of grams of CO that can react with .150kg of Fe2O3?

Valence electron of pd, Valence electron of pd Pd has ten valence elect...

Valence electron of pd Pd has ten valence electrons in the neutral atom.   There are no charges and no X-type ligands in the complex; as, this is a d 10 complex.

Write down the molecular formula of the oxidation reaction, Write down the ...

Write down the molecular formula of the overall oxidation reaction of a fatty acid in these three reaction cascades. What roles do A and B play in these reaction cascades?

The four quantum numbers of the outermost orbital, The four quantum numbers...

The four quantum numbers of the outermost orbital of K (atomic no. =19) are: (1)  n= 2, l= 0, m=0, s= +1/2           (2) n= 4, l= 0, m=0, s= +1/2          (3) n= 3, l= 1,

Position of the substituent - iupac system of nomenclature, Position of the...

Position of the substituent - IUPAC system of nomenclature Number of the carbon atoms in the base chain like 1, 2, 3,....... etc. starting from the end that gives lower numb

.Dienes, Physical properties of dienes

Physical properties of dienes

Draw a temperature-composition phase diagram, Q. Use the following informat...

Q. Use the following information to draw a temperature-composition phase diagram for the binary system of H 2 O (A) and Na 2 SO 4 (B) at p = 1 bar, confining t to the range 20 to

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd