Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
As already discussed, the reduction of the metallic oxide usually heating it with some reducing agent such as carbon, carbon monoxide, hydrogen or some other metal. The reducing agent joins with oxygen of the metal oxide.
M2O2 + yC xM +yCO Some metals oxides get reduced easily while others are reduced with difficulty. Some oxides are condensed at relatively low temperatures while others are reduced at relatively high temperatures. Thermodynamic considerations play an important role in deciding the temperature and the choice of reducing agent in the thermal reduction during metallurgy. For a spontaneous process, the changes in Gibbs energy ΔG must be negative. The changes in Gibbs energy ΔG for any process at any specific temperature, is described by the equation ΔG = ΔH - TΔS Where, ΔH is the enthalpy change T is the absolute temperature and ΔS is the entropy change for the process. For any reaction, this change could also be described from the equation: ΔG° = RTInK Where, K is the equilibrium constant of the 'reactant product' system at temperature T. a negative value of ΔG implies a positive value of K. Consider a reaction, the randomness of the system decreases because the gases have more randomness than solids. Hence, ΔS for this reaction is negative. Thus, if temperature is increased then TΔS becomes more negative. Since TΔS is subtracted in equation, ΔGbecomes less negative. On the other hand, if ΔS is positive, on increasing the temperature of ΔG decreased and becomes more negative. For example, in the reaction, 2C (s) + O2 (g) 2CO (g) ΔS is positive and ΔG decreases and becomes more negative as the T increases. If the reactants and products of two reactions are put together in a system and the net Gibbs free energy change, ΔG of the two possible reactions is negative, and then the overall reaction will occur. Thus, the process of interpretation of feasibility of a process involve coupling of the reactions, calculating the sum of their ΔG and then observing the magnitude and sign of ΔG. Such coupling is easily understood in the form of Ellingham diagram.
The interionic attraction depends on interaction of: (1) Solute-Solute (2) Solvent-Solvent (3) The charges (4) Molecular proper
Q. Explain the electronic distribution complexes? In majority of the cases the decrease in the number of unpaired electrons agrees well with the magnetic moment values obtained
Explain The compound decarboxylates The compound decarboxylates; it is a disubstituted malonic acid in which the two a substituents are connected within a ring. The net effect
Determine the Coordination number (CN) of HCP In HCP unit cell, the base centered atom touches six corner atoms in the similar plane, three atoms in a plane above and thre
Q. Factors affecting development of a new product? The product development and marketing is not just selling a product, but is a highly multi-disciplinary domain comprising of
The magnetic quantum number for an electron when the value of principal quantum number is 2 can have: (1)3 values (2) values (3)9 values (4)6 values Ans: 3 values
what are the properties of acid halides
THE VOLUMETRIC DETERMINATION OF A GIVEN ACETIC ACID SOLUTION REQUIRED BY USING 100 ML. OF A STANDARD CAUSTIC SODA SOLUTION. Compound Microscope 1. Procedure for st
If 4.5 grams of Nitrogen reacted with 2.6 grams of Hydrogen, identify the following: Limiting Reactant- Excess Reactant- and Theoretical Yield:
Q. What do you mean by Acid Value and Free Fatty Acids? Acid value is a measure of hydrolytic rancidity present in the sample of oil/fat. It reflects the state of freshness o
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +1-415-670-9521
Phone: +1-415-670-9521
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd