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Van der Waals repulsions
Because severe van der Waals repulsions occur among the tert-butyl groups in compound A at normal bond lengths and angles, the only way for the molecule to relieve these repulsions is to stretch the appropriate bonds and flatten itself by widening the C-C-C angles. The observed structure is a compromise among the Scylla of van der Waals repulsions and the Charybdis of nonoptimal bond lengths and angles.
Advantages of radiometric titration
E1cb means elimination, unimolecular, of the conjugate base. This type elimination proceeds through the carbanion mechanism. An carbon compound, acting as an acid, is attacked by
dickman
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role of modifiers in solvent extraction of metal ion
Effects of substituents on the acidity of phenols: Existence of electron attracting group, (for example -NO 2 , -X, - NR + 3 , -CN, -CHO, -COOH) on the benzene ring increases
Disperse dyes: These dyes are utilized to colour synthetic fabrics for example orlon, polyesters, nylon and cellulose acetate that comprise tightly bounded structures. The dyes
characteristics
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