Tin and lead, Chemistry

Assignment Help:

 

GROUP 14: TIN AND LEAD

Tin and lead give some resemblance to the lighter elements in group 14, especially Ge. Although they are uniquely more metallic in their physical and chemical characteristics, simple cationic chemistry is the exception rather than the rule. As with group 13, two oxidation states MIV and MII are found, the MII form giving more stable for lead.

Both substances have rather low abundance, but are commoner than other heavy metals. They occur in the minerals galena PbS and cassiterite SnO2. They each have various stable isotopes, Sn more than any other element (10). Some Pb isotopes are discovered from the radioactive decay of uranium and thorium. The isotopic composition of Pb (and thus its atomic mass) differs detectably according to the source, and such variations have been used to estimate the age the Earth of and of rocks.

The elements are readily made by reduction of their ores and are soft, low-melting, somewhat unreactive metals. Tin is required for plating, and both elements in low-melting alloys and as many elements. Applications of lead are declining as its substances are very toxic. A continuing major need is in leadacid batteries, which depend on two reactions involving the PbII, Pb0 and PbIV states:

 

988_Untitled.png

Occurring at different electrodes, these show a cell potential of 2 V, greater than can be obtained easily from any other pair of electrode reactions in aqueous solution


Related Discussions:- Tin and lead

Equlant mass, find the equlant mass of 2M HCL?

find the equlant mass of 2M HCL?

Determine the spectral lines correspond to paschen series, The emission spe...

The emission spectrum of hydrogen is found to satisfy the expression for the energy change. teiangle E  (in joules) such thatTriangle E= 2.18x10(1/n 2 1 - 1/ n 2 1 ) J  where n

Stearic effect - reactivity of aldehydes and keto, Stearic effect - relativ...

Stearic effect - relative reactivity of aldehydes and keto The size of the alkyl group is much more than that of hydrogen. In aldehydes, there is one alkyl set although in keto

Thermometric titration, question..give brif instrumentation of thermometric...

question..give brif instrumentation of thermometric titration

Helium balloon at a pressure, A 10L helium balloon at a pressure of two bar...

A 10L helium balloon at a pressure of two bar at 27C. Some O 2 is now inside in balloon and final volume is made 30L. the pressure also fell to 1 bar at similar temperature. the p

Physical properties of dihydrogen, I want information on physical propertie...

I want information on physical properties of dihydrogen

Glucose is soluble in water but cyclohexane is not.why?, Glucose and Sucros...

Glucose and Sucrose are soluble in water because they are polar compounds.SO they are soluble in polar compounds like water. Cyclohexane and Benzene are non polar compounds.They ar

Ionic radii, Ionic Radii   The experimentally calculated anion-cation...

Ionic Radii   The experimentally calculated anion-cation distances in highly ionic solids have to be interpreted on the assumption that each and every ion has a nearly fixed

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd