Thermodynamic , Physics

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Given the following thermodynamic information, develop the Ag-CN-H2O Eh-pH diagram for a solution containing 1 × 10-3 M [Ag] and 5 × 10-3 M [CN] at 25oC. Please show all work

SPECIES

ΔGo, kcal/mol

Ago

0.00

Ag+

18.44

AgO

3.50

Ag2O3

29.01

AgO2

-2.63

Ag2O

-2.68

Ag(CN)2-

73.04

HCN

26.77

CN-

39.67

H2O

-56.69

 

 


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