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Thermal spelling: The breaking or cracking or peeling off the refractory is known as spelling. A good refractory must show a good resistance to thermal spelling. Thermal spelling can be decreased by minimizing the development of internal stress by:
(1) Using refractory with high porosity, good thermal conductivity and low coefficient of expansion.
(2) Avoiding sudden temperature changes.
(3) Proper furnace design
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For the binary system 2, 4-dimethylpentane (1) + benzene (2) the excess Gibbs energy of the liquid phase is given by: G E /(x 1 x 2 ) = (A 12 x 1 + A 21 x 2 ) a. Calculate t
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