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The structure of spiropentadiene
The structure of spiropentadiene is shown below; it undergoes a Diels-Alder reaction with two molar equivalents of 1,3-cyclopentadiene. Spiropentadiene is unstable because of its great ring strain. Although cyclopropane rings are retained in the product, they have less ring strain than cyclopropene rings.
A crucial step in the Robinson annelation is the elimation of an aldol adduct to form an enone. The elimination of an aldol product can occur in base (it occurs even more readily i
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The ketone is more stable than its enol Because the ketone is more stable than its enol, more energy must be expended for it to ionize. Consequently, the ketone is less aci
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