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The band model of solids is an extended of the molecular orbital (MO) method. The overlap of atomic orbitals in an extended solid produces rise to continuous bands of electronic energy levels associated with different degrees of bonding. In a simple monatomic solid the bottom of the band is build up of orbitals bonding between all neighboring atoms; orbitals at the top of the band are antibonding, and levels in the middle have an intermediate bonding character. Different atomic orbitals may, in principle, give rise to different bands, although they may overlap in energy.
Fig. 1. Band picture for (a) nonmetallic and (b) metallic solid; occupied electronic levels are shown shaded.
Increases in temperature approximately in accordance with the Arrhenius equation used in chemical kinetics.
the order of stability of carbocations and carbanions For carbocation 3 degree > 2 degree > 1 degree for carbanion 1 degree > 2 degree > 3 degree
give answer
The ionisation potential of a hydrogen atom is -13.6 eV. What will be the energy of the atom corresponding to n= 2 . (1) -3.4 eV (2)-6.8 eV (3) -1.7 eV
why wood doesnot sublimine ?
preparation reaction of esters
Q. How many centigrams are in 5 kilograms? Two conversion factors are essential to solve this problem. Keep in mind that there are 1000 grams in a kilogram and 100 centigrams i
A 200g golf ball is moving with a speed of 5 m per hour. The associated wave length (h = 6.625 x 10 -34 J sec)is: (1) 10- 1 0 m (2) 10 -20 m
How acidic character varies in s block elements
Which forms a crystal of Nacl: (1) Nacl molecules (2) Na + and cl - ions (3) Na andcl atoms (4) None of the above Ans: Na + and cl - ions
What are laws of crystallography?How it helps us in the study of crystal structure
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