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The abstraction of a hydrogen atom
The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 438 = 90 kJ mol-1. (These numbers are from Table 5.3 with the bond energy of CH3O-H as an approximation for that of (CH3)3CO-H.) The first initiation step, formation of the tert-butyloxy radical from a peroxide, is also endothermic. Because both initiation steps are highly endothermic, the reaction is not likely to generate a high enough concentration of radicals to initiate a chain reaction.
s block
fajan''s law
A mol 4:1 mixture of He and CH4 is contained in vessel at 20 bar pressure.Due to a hole in the vessel the gas mixture leaks out.the composition of the mixture,effusing out initiall
Streptomycin: It was discovered in the year 1944 by Waksman. Streptomycin is successful against tuberculosis. It is as well used for other general infections such as ears, thro
Take these values into account and comment on the relation between the heat of formation of the gases and the vibrational frequencies again.
difference between edta and clark method
assignment
Flash point - Characteristics of Hydrocarbons The minimum temperature at which an oil provides enough vapours to form an explosive mixture with air is considered as flash point
Principle of atomic fluorescence spectrometry: In AFS, the analyte is converted within gaseous atoms in the ground state using a appropriate atomization technique. These are t
Initially 5 mol of an ideal gas with Cv,m=12.5 J K^-1 mol^-1 are at a volume of 5 dm^3 and a temperature of 300K. If the gas is heated to 373 K and the volume changed to 10 dm^3, w
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