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The abstraction of a hydrogen atom
The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 438 = 90 kJ mol-1. (These numbers are from Table 5.3 with the bond energy of CH3O-H as an approximation for that of (CH3)3CO-H.) The first initiation step, formation of the tert-butyloxy radical from a peroxide, is also endothermic. Because both initiation steps are highly endothermic, the reaction is not likely to generate a high enough concentration of radicals to initiate a chain reaction.
Q. Explain Le Chtelier's Principle Ans. Consider the equilibrium reaction of: A + B -> C + D The forward reaction occurs when A and B combine to form C and D: A +
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application of crystallography
Oxidation Reduction Titrations The titrations based upon oxidation-reduction reactions are termed redox titrations. The chemical reactions proceed along with transfer of electr
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