The abstraction of a hydrogen atom, Chemistry

Assignment Help:

The abstraction of a hydrogen atom

The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 438 = 90 kJ mol-1. (These numbers are from Table 5.3 with the bond energy of CH3O-H as an approximation for that of (CH3)3CO-H.) The first initiation step, formation of the tert-butyloxy radical from a peroxide, is also endothermic.  Because both initiation steps are highly endothermic, the reaction is not likely to generate a high enough concentration of radicals to initiate a chain reaction.

 


Related Discussions:- The abstraction of a hydrogen atom

Explain working of mass spectrometry, Describe the principle and working of...

Describe the principle and working of Mass spectrometry with suitable diagram along with its applications. Definition of Mass Spectrometry Show the principle and working

Cooking is prefered in a pressure cooker than in open vessel, To increase t...

To increase the pressure so that boiling point of water increases and heat provided goes only for cooking food not for boiling water

Kmno4, Why the kmno4 is colored.?

Why the kmno4 is colored.?

Antifertility, how can they used and what its side effects?

how can they used and what its side effects?

Illustrate about werners theory, Q. Illustrate about Werners Theory? Ba...

Q. Illustrate about Werners Theory? Based on the study of a large number of compounds. Wermer gave the following postulates: • Metal atoms in complexes possess two types o

Analytical test of oxalic acid or polyprotic acid, Analytical test of Oxali...

Analytical test of Oxalic acid or Polyprotic acid (a) The aqueous solution turns blue litmus red. (b) The aqueous solution includes effervescences along with NaHCO 3 . (c

Need of tar, If you have not used tar before, try this sequence to makeanar...

If you have not used tar before, try this sequence to makeanarchive ofyour llast project: %cd;tar cf llast.tar llast %tar tfv llast.tar The first line m vesyou to your hom

Electroanalytical technique, Electroanalytical technique: An electroan...

Electroanalytical technique: An electroanalytical technique is based on the measurement of one or more electrical quantities and their magnitudes could be correlated with the

Transport number, how to calculate transport number by moving boundary meth...

how to calculate transport number by moving boundary method

Calorimetry, An unknown amount of copper, at 95 degrees C,, is placed in 10...

An unknown amount of copper, at 95 degrees C,, is placed in 100 g of water at 20 degrees C. It reaches temperature equilibrium at 60 degrees C. What is the mass of the copper?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd