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The abstraction of a hydrogen atom
The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 438 = 90 kJ mol-1. (These numbers are from Table 5.3 with the bond energy of CH3O-H as an approximation for that of (CH3)3CO-H.) The first initiation step, formation of the tert-butyloxy radical from a peroxide, is also endothermic. Because both initiation steps are highly endothermic, the reaction is not likely to generate a high enough concentration of radicals to initiate a chain reaction.
Physical properties of dienes
A red flame is produced when LiCl is heated. How can I determine which transition between the energy levels produces this colour?
There are numerous methods for shielding metals from corrosion (iron from rusting). Some of these methods are being discussed as follows: 1. Barrier protection; in this me
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applications of photochemistry
i want all the information of all the periods from 13th to 18th present in p block element
ionic bond
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