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Cis-1,3-di-tert-butylcyclohexane can exist in a chair conformation (A) in which both tert-butyl groups are equatorial. Though, in either chair conformation of trans-1,3-di-tert-butylcyclohexane (B), there is an axial tert-butyl group. The axial tert-butyl group can be avoided if compound B exists in a twist-boat conformation C. in which both tert-butyl groups are equatorial. Evidently the twist-boat conformation is more stable than either chair conformation having an axial tert-butyl group. The interaction of the methyl groups with the ring hydrogens should be about the similar in both conformations A and C, so that these cancel in the comparison.
what is the theoretical background of the topic?
What do you understand by molar conductivity at infinite dilution
DEGREE OF HARDNESS: The degree of hardness of water is conveniently expressed in terms of equivalent amount of CaCO 3 . Although hardness of water is never present in th
first two groups are metal but why hydrogen is placed in first group
Give the name of the molecular shape of each of the following. (1 mark each) 1) silicon tetraiodide
hybridisation of o in boric acid
dithiazone.
what is acid
Fe3+ + e ------> Fe2+
Characteristics of tautomerism (a) Tautomerism (cationotropy) is caused by the oscillation of hydrogen atom between two polyvalent atoms present in the molecule. The modificati
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