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Structure of Aldehydes and Ketones
Carbonyl carbon atom is connected to three atoms by sigma bonds. As these bonds use Sp2-orbitals, they found in the same plane and are 120° apart. The carbon-oxygen double bond is dissimilar than carbon-carbon double bond. As, oxygen is extremely electronegative, the electrons of the covalent bond are attracted towards oxygen. Accordingly, oxygen retains a partial negative charge and carbon a partial positive charge creation the bond polar. The largest value of dipole moment,
It is illustrated that carbonyl set is a resonance hybrid of the subsequent two structures.
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SILENT FEATURES OF ELECTROCHEMICAL SERIES.
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The interatomic distances in H 2 and Cl 2 molecules are 74 and 198 pm respectively. The bond length of HCl is : (1) 272 pm (2) 1
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