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Consider 1:1 stoichiometric polymerisation of 1,4-diaminobutane with sebacoyl chloride.
(a) Write down a balanced chemical equation for the polymerization
(b) Name the polymer formed by this polymerization.
(c) Calculate the extent of reaction required to produce this polymer with a number-average molar mass of 8000.
(d) What would happen if you included 1,1,4,4-tetraaminobutane in the polymerisation so that the stoichiometric ratio was 1:2:4 tetraaminobutane:diaminobutane:sebacoyl chloride?
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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s]
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