State differences between primitive cells and unit cells, Chemistry

Assignment Help:

What are similarities and differences of primitive cells and unit cells? 

Ans:  Unit  cell  is  the  basic  building  block  of  a  crystal,  repeated  infinitely  in  three dimensions.

It's characterized by the three vectors (a, b, c) that form edges of a parallelopiped and the angles between the vectors (alpha, angle between b and c; beta, the angle between a and c; gamma, angle between a and b).

A primitive cell is a unit cell built on the basis vectors of a primitive basis of direct lattice, namely a crystallographic basis of the vector lattice L such that each lattice vector t of L may be obtained as an integral linear combination of basis vectors, a,  b,  c. It comprise only one lattice point and its volume is equal to the triple scalar product (a, b, c).

Non-primitive bases are used usually to illustrate centered lattices. In that case, unit cell is a multiple cell and it contains more than one lattice point. Multiplicity of the cell is given by the ratio of its volume to volume of a primitive cell.

 


Related Discussions:- State differences between primitive cells and unit cells

Rancidification - chemical properties of oils and fats, Rancidification - c...

Rancidification - chemical properties of oils and fats On long storage in contact along with air and moisture, oils and fats develop unlikable smell. The process is termed as r

Explain the stability factors for co-ordination compounds., The formation o...

The formation of a co-ordination compound involves reaction between a metal ion and ligands. If the force of attraction of the metal ion with ligands is strong a stable complex may

Applications of flame photometry, Applications of flame photometry: A ...

Applications of flame photometry: A few common applications of flame photometry are given below. Flame photometry could be used to detect the presence of the elements o

Entropy change for the reaction., The standard free energy change for a rea...

The standard free energy change for a reaction is -212.3 kJ mol -1 . If the enthalpy of the reaction is - 216.7 kJ mol -1 , calculate the entropy change for the reaction.

Preparation of alkanes, preparation of ethane with suitable equations (hydr...

preparation of ethane with suitable equations (hydrogenation

The electronic configuration of copper, The electronic configuration of cop...

The electronic configuration of copper (29 cu) is: (1)1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 6 , 3d 9 , 4s 2   (2) 1s 2 , 2s 2 , 2p 6, 3s 2 , 3p 6 , 3d 10 , 4s 1 (3) 1s 2 , 2s

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd