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Stability of gem diols lies on the following factors:
(a) Steric hindrance by +I group around α-carbon decreases the stability of gem diols. +I group decreases stability of gem diol and therefore decreases extent of hydration.
(b) Stability of gem diols mainly relies on the existence of -I group on α-carbon. More is the -I power of the group much more will be stability of gem diols.
(c) Intramolecular hydrogen bonding raises stability of gem diols. -I set depicts on carbon having gem diol group increases strength of hydrogen bond.
Much more is the power of hydrogen bond more will be the stability of gem diol.
What are the basic physical and chemical properties of this group
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