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The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measuring magnetic moments. Predict the spin-only magnetic moment, in Bohr magnetons, that you would expect for each spin state.
An aqueous solution of cobalt (III) is diamagnetic. In the presence of excess fluoride ion, the above cobalt solution becomes paramagnetic. Use CFT arguments to give an explaination for this observation.
NiCl42- responds strongly to an external magnetic field while NiCN42- responds barely at all.
Explain how this information can be used to show that the two complexes possess differing geometries for their ligands about the metal center.
The complex Cr(H2O)63+ has high symmetry (Oh) while the complex Cu(H2O)62+ is seen to adopt lower symmetry ( D4h). Give an explaination for this observation.
Nomenclature of spiro compounds Compounds where one carbon atom is common to two dissimilar rings are known as spiro compounds. The IUPAC or International Union of Pure and App
Nitrous acid (HNO2) is an unstable compound when prepared by the following reaction: HCl (g) + NaNO2 (s) ? HNO2 (l) + NaCl (s). As the product of the above reaction is unstable, t
Q. Calculate the Slope of a Line from Data Points? Compute the slope of a line that contains these data points (3.0 cm 3 , 6.0 g) and (12 cm 3 , 24 g). To compute the slope of
Q. Ca +2 = 20 ppm, Mg +2 = 25 ppm, CO 2 = 30 ppm, HCO - 3 = 150, K + = 10 ppm. Calculate the lime (87% pure) and soda (91% pure) required softening 1 million litt
The role of prion in BSE
Anomalous behaviour of carbon and silicon
Which of the following is an incorrect representation for a neutral atom: 108/47Ag 63/30Cu 30/15P 13/6C 6/3Li
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The quantum number which specifies the location of an electron as well as energy is : (1) Principal quantum number (2) Azimuthal quantum number (3) Spin quantum number
WHY ELEMENT BELONGING TO GROUP 3 TO 12 ARE CALLED TRANSACTION ELEMENT
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