Set of quantum numbers is not possible for 4p electron, Chemistry

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Which one of the following set of quantum numbers is not possible for 4p electron:

(1) n=4, l=1, m=-1, s= +1/2

(2) n=4, l=1, m=0, s= +1/2

(3) n=4, l=1, m=2, s= +1/2

(4) n=4, l=1, m=-1, s= +1/2

Ans: n=4, l=1, m=2, s= +1/2

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