Resonance, Chemistry

Assignment Help:

 

Sometimes more than one valence structure is possible and there shows to be no unique assignment. A familiar organic example is in the disposition of single and double C-C bonds in benzene. In the carbonate ion 11) the three structures shown are equivalent by symmetry, and experimentally all three C-O bonds have same length. We describe this situation as resonance between the different structures, and represent it by the double headed arrows shown in 11. The term is misleading as it suggests a fast oscillation between different structures, which certainly does not happen. It is better to think of a wavefunction that is contracted by combining the structures, none of which on their own describe the bonding correctly.

 

 

2244_Untitled.png

                                   11

Resonance may also be appropriate with different valence structures that are not equivalent but look equally plausible, as in nitrous oxide (N2O 12).

 

 

1588_Untitled.png


Related Discussions:- Resonance

Relative density of mercury, The temperatre of an air bubble while rising f...

The temperatre of an air bubble while rising from bottom to surface of lake remains constant but its diameter is doubled . if the pressure is equivalent to h meter of mercury colum

Define the hydration rate, The hydration rate of the deuterium-substituted ...

The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limi

Calculate the density of ethanol, A 100 gal tank contains 10 lb of water. T...

A 100 gal tank contains 10 lb of water. The tank is filled by two inlet streams, one of pure water and one of pure ethanol. The flow rate of both streams is 10 gal/min. Calculate t

Neverwet, I have a question on hydrophobicity. I have a product called Neve...

I have a question on hydrophobicity. I have a product called Neverwet that creates a hydrophobic surface on stuff. There''s a base and top spray. The top spray thats mainly acetone

Physical chemistry homework help, For 1D particle in a box wave functions i...

For 1D particle in a box wave functions in a box of length L, evaluate a formula for the average energy in terms of the quantum number n: =?0L?*Hˆ?dx

Physical properties of succinic acid, Physical properties of Succinic Acid ...

Physical properties of Succinic Acid  (a) Succinic Acid is a white crystalline solid. It melts at 188° C (b) Succinic Acid is less soluble in water. It is comparatively more

Oxidation and reduction, Definitions  Oxidation exactly meant 'combinat...

Definitions  Oxidation exactly meant 'combination with oxygen' and reduction 'removal of oxygen'. These definitions have been illustrated. Oxidation implies combination with a

AAS, DISAVANTAGES OF FLAME AAS

DISAVANTAGES OF FLAME AAS

Llimitations of werners theory, Q. Llimitations of werners theory? Ther...

Q. Llimitations of werners theory? There were inherent limitations with such a simple approach. For example, the following experimental facts cannot be explained on the basis o

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd