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Sometimes more than one valence structure is possible and there shows to be no unique assignment. A familiar organic example is in the disposition of single and double C-C bonds in benzene. In the carbonate ion 11) the three structures shown are equivalent by symmetry, and experimentally all three C-O bonds have same length. We describe this situation as resonance between the different structures, and represent it by the double headed arrows shown in 11. The term is misleading as it suggests a fast oscillation between different structures, which certainly does not happen. It is better to think of a wavefunction that is contracted by combining the structures, none of which on their own describe the bonding correctly.
11
Resonance may also be appropriate with different valence structures that are not equivalent but look equally plausible, as in nitrous oxide (N2O 12).
The equation Δ x Δp ≥ h/ 4Π shows: (1) de-Broglie relation (2) Heisenberg's uncertainty principle (3) Aufbau principle (4) Hund's rule ans: Heisenberg'
The known metal ion solution used contains 0.10 M of each of the six metal ions (i.e. 0.10 M Ag+ and 0.10M Pb2+). An equal volume of 3 M HCl and the known solution are mixed. What
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1. A sample of water contains: suspended matter = 100 mg; Ca(NO3)2 = 16.4 mg/L; MgSO4 = 24 mg/L; MgCl2 = 19 mg/L; NaOH = 40 mg/L and KOH = 56 mg/L. Calculate temporary, permanent a
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Tert-butylamine Tert-butylamine cannot be prepared by the Gabriel synthesis because it would require that the nitrogen of phthalimide be alkylated with tert-butyl bromide in an
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Halogen Containing Compounds Compounds that are derived from hydrocarbons by the replacement of one or more than one hydrogen atoms by the corresponding number of halogen atoms
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