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Sometimes more than one valence structure is possible and there shows to be no unique assignment. A familiar organic example is in the disposition of single and double C-C bonds in benzene. In the carbonate ion 11) the three structures shown are equivalent by symmetry, and experimentally all three C-O bonds have same length. We describe this situation as resonance between the different structures, and represent it by the double headed arrows shown in 11. The term is misleading as it suggests a fast oscillation between different structures, which certainly does not happen. It is better to think of a wavefunction that is contracted by combining the structures, none of which on their own describe the bonding correctly.
11
Resonance may also be appropriate with different valence structures that are not equivalent but look equally plausible, as in nitrous oxide (N2O 12).
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Why does NO2 dimerise? a) Give an example of linkage isomerism. b) A solution of KOH hydrolyses CH3CH2CH2CH2Cl and CH3CH2CH2Cl. Which one of these is more easily hydrolysed?
What is difference between silica used in TLC and HPLC column? TLC is called thin layer chromatography. The simple technique works on the principle of adsorption, where as HPLC i
The radius of first Bohr's orbit for hydrogen is 0.53 Å. The radius of third Bohr's orbit would be: (1) 0.79 Å (2) 1.59 Å (3) 3.18 Å (4)4.77 Å
WHAT ARE SOLUBILITY?
why is the valence electron 4s2 in the elelment Sc21 and not 3d1?
westron
Ask question #Minimum 100 wordefine-coordination-position-isomerism ds accepted#
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